13610-06-5

Basic information

• Product Name: Benzene, [(1-methyl-2-propynyl)thio]-
• CAS NO: 13610-06-5
• Molecular Formula: C10H10S
• Molecular Weight: 162.255
• Mol File: 13610-06-5.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-methyl-2-propynyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-methyl-2-propynyl)thio]-(13610-06-5)
• EPA Substance Registry System: Benzene, [(1-methyl-2-propynyl)thio]-(13610-06-5)

Safety Data

• Hazardous Substances Data: 13610-06-5(Hazardous Substances Data)

Upstream product

• 59967-06-5 1-methylprop-2-ynyl methanesulfonate 
• 108-98-5 thiophenol 
• 113647-42-0 3-Bromo-but-1-yne 
• 930-69-8 sodium thiophenolate 

Downstream Products

• 1424999-28-9 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)but-1-en-2-yl)-1,3,2-dioxaborolane 
• 123209-26-7 1-<<1-methyl-2-<(1-methyl-2-propenyl)oxy>-2-propenyl>sulfonyl>benzene 
• 123209-23-4 1-<<1-methyl-2-(2-propenyloxy)-2-propenyl>sulfonyl>benzene 
• 1595-39-7 1,2-butadien-3-yl phenyl sulfide 
• 13603-88-8 <2-butynylsulfonyl>benzene 

Relevant articles and documents

Gold-Catalyzed Oxidative Hydrative Alkenylations of Propargyl Aryl Thioethers with Quinoline N-Oxides Involving a 1,3-Sulfur Migration

This work reports gold-catalyzed oxidative alkenylations of quinoline N-oxides with propargyl aryl thioethers to afford 3-hydroxy-1-alkylidenephenylthiopropan-2-one via a 1,3-sulfur group migration. The mechanism of this reaction is postulated to involve

Photochemical Doyle-Kirmse Reaction: A Route to Allenes

This Letter describes the metal-free, blue-light-induced [2,3]-sigmatropic rearrangement of sulfonium ylides generated from donor/acceptor diazoalkanes and propargyl sulfides. The reaction furnishes highly functionalized allenes from a broad range of starting materials in decent yield. Mechanistic experiments supported by the literature data suggest singlet carbenes as intermediates in this reaction.

Unique Reactivity of α-Substituted Electron-Deficient Allenes using Sulfinate Salts as Lewis Base Organocatalysts

The efficient sulfinate-catalyzed intermolecular addition reaction of α-substituted allenyl sulfones and allenoates with Michael acceptors is highlighted. The sequence proceeds under mild conditions to provide a scalable and efficient access to versatile

Formal regiocontrolled hydroboration of unbiased internal alkynes via borylation/allylic alkylation of terminal alkynes

In accessing trisubstituted vinyl boronates from terminal alkynes, a propargyl directing (2-pyridyl)sulfonyl group allows terminal alkynes to undergo Cu-catalyzed B2(pin)2-borylation and subsequent Cu-catalyzed allylic alkylation wit

Amination and [2,3]-sigmatropic rearrangement of propargylic sulfides using a ketomalonate-derived oxaziridine: synthesis of N-allenylsulfenimides.

Amination of propargylic sulfides with a ketomalonate-derived oxaziridine under metal free conditions gives N-Boc-N-allenylsulfenimides via [2,3]-sigmatropic rearrangement.

Studies on the Addition of Allyl Oxides to Sulfonylallenes. Preparation of Highly Substituted Allyl Vinyl Ethers for Carbanionic Claisen Rearrangements

Thirty-five allyl vinyl ethers bearing an arylsulfonyl anion-stabilizing group have been prepared by addition of allylic alkoxides to (arylsulfonyl)allenes.The allyl vinyl ethers are produced as either β,γ-unsaturated or α,β-unsaturated sulfones depending upon the substitution pattern of the allene and the reaction conditions.A wide variety of substitution patterns are available by using this method.Factors that control the position and stereochemistry of the vinyl ether double bond are discussed.