1361052-05-2Relevant academic research and scientific papers
Guanidine electron donors and silver halides: Interplay and competition between redox, coordination and polymerization reactions
Emeljanenko, Dimitri,Horn, Julian,Kaifer, Elisabeth,Wadepohl, Hubert,Himmel, Hans-Joerg
, p. 695 - 704 (2012/04/04)
Redox reactions compete with coordination and polymerization reactions when the organic electron donor and ligand, 1,2,4,5-tetrakis(tetramethylguanidino) benzene (1), is dissolved together with silver halides AgX (X = Cl, Br or I) in solvents of different polarity. The complex results obtained for the relatively simple system 1/AgX highlight the importance of solvent effects. A variety of chain polymers have been synthesized in which the guanidine electron-donor building blocks are connected by silver halide clusters of different sizes. Copyright
