136106-33-7Relevant academic research and scientific papers
Palladium-Catalyzed Oxidative Borylation of Allylic C-H Bonds in Alkenes
Mao, Lujia,Bertermann, Rüdiger,Rachor, Simon G.,Szabó, Kálmán J.,Marder, Todd B.
supporting information, p. 6590 - 6593 (2017/12/26)
This communication describes an efficient palladium pincer complex-catalyzed allylic C-H borylation of alkenes. The transformation exhibits high regio- and stereoselectivity with a variety of linear alkenes. A synthetically useful feature of this allylic C-H borylation method is that all allyl-Bpin products can be isolated in usually high yields. Preliminary mechanistic studies indicate that this C-H borylation reaction proceeds via Pd(IV) pincer complex intermediates.
Stereoselective addition of allylstibonium bromide to aldehydes
Huang, Yao-Zeng,Zhang, Li-Jun,Chen, Chen,Guo, Guang-Zhong
, p. 47 - 52 (2007/10/02)
Reaction of allylantimony with aldehydes provides homoallylic alcohols with high threo selectivity in the case of (E)-4-methyl-2-pentenylantimony (2c) and with preferential erythro selectivity in the case of crotylantimony (2a).
