1361089-83-9Relevant academic research and scientific papers
Nickel-catalyzed enantio- and diastereoselective three-component coupling of 1,3-dienes, aldehydes, and a silylborane leading to α-chiral allylsilanes
Saito, Nozomi,Kobayashi, Ayami,Sato, Yoshihiro
supporting information; experimental part, p. 1228 - 1231 (2012/03/11)
Three-in-one: The nickel-catalyzed asymmetric three-component coupling of 1,3-dienes, aldehydes, and a silylborane in the presence of a chiral phosphoroamidite ligand has been realized. The reaction proceeds by σ-bond metathesis of an oxanickelacycle intermediate with the silylborane to afford the corresponding α-chiral allylsilane derivative in a highly diastereo- and enantioselective manner. Copyright
