337367-49-4

Basic information

• Product Name: Benzene, 1-(1E)-1,3-butadienyl-4-[(methoxymethoxy)methyl]-
• CAS NO: 337367-49-4
• Molecular Formula: C13H16O2
• Molecular Weight: 204.269
• Mol File: 337367-49-4.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1E)-1,3-butadienyl-4-[(methoxymethoxy)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1E)-1,3-butadienyl-4-[(methoxymethoxy)methyl]-(337367-49-4)
• EPA Substance Registry System: Benzene, 1-(1E)-1,3-butadienyl-4-[(methoxymethoxy)methyl]-(337367-49-4)

Safety Data

• Hazardous Substances Data: 337367-49-4(Hazardous Substances Data)

Upstream product

• 207223-84-5 {4-[(methoxymethoxy)methyl]phenyl}methanol 
• 127653-30-9 (4-methoxymethoxymethylphenyl)-methanal 
• 104292-95-7 methyl 4-<(methoxymethoxy)methyl>benzoate 
• 401814-46-8 (E)-3-(4-methoxymethoxymethylphenyl)acrylic acid methyl ester 
• 401814-47-9 (2E)-3-(4-methoxymethoxymethylphenyl)-2-propen-1-ol 

Downstream Products

• 1001187-05-8 C₃₁H₃₃F₃O₆ 
• 1361090-01-8 C₃₅H₄₃F₃O₅Si 
• 1361090-00-7 C₃₅H₄₃F₃O₅Si 

Relevant articles and documents

Nickel-catalyzed intermolecular coupling of 1,3-dienes and aldehydes via transmetalation of nickelacycles with diisobutylaluminum acetylacetonate

Intermolecular coupling reactions of 1,3-dienes and aldehydes via transmetalation of nickelacycle intermediate with iBu2Al-acac were investigated. In the reactions, a linear adduct or a branched adduct was produced, depending upon the nature of 1,3-dienes and aldehydes, via two nickelacycles that were relatively stable among the four possible nickelacycles because of the equilibrium with π-allynickel forms.