1361090-00-7

Upstream product

• 337367-49-4 1-[(E)-buta-1,3-dienyl]-4-(methoxymethoxy-methyl)benzene 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 1361089-82-8 (3S,5R,6E)-5-dimethylphenylsilyl-7-(4-methoxymethoxymethylphenyl)-2-methylhept-6-en-3-ol 
• 17257-71-5 (S)-Mosher acid 

Relevant academic research and scientific papers

Nickel-catalyzed enantio- and diastereoselective three-component coupling of 1,3-dienes, aldehydes, and a silylborane leading to α-chiral allylsilanes

Three-in-one: The nickel-catalyzed asymmetric three-component coupling of 1,3-dienes, aldehydes, and a silylborane in the presence of a chiral phosphoroamidite ligand has been realized. The reaction proceeds by σ-bond metathesis of an oxanickelacycle intermediate with the silylborane to afford the corresponding α-chiral allylsilane derivative in a highly diastereo- and enantioselective manner. Copyright