1361098-27-2Relevant academic research and scientific papers
Cross dehydrogenative coupling of: N -aryltetrahydroisoquinolines (sp3 C-H) with indoles (sp2 C-H) using a heterogeneous mesoporous manganese oxide catalyst
Dutta,Sharma,Sassu,Dang,Weerakkody,Macharia,Miao,Howell,Suib
supporting information, p. 5350 - 5355 (2017/11/22)
We disclose a novel, heterogeneous catalytic approach for selective coupling of C1 of N-aryltetrahydroisoquinolines with C3 of indoles in the presence of mesoporous manganese oxides. Our work involves a detailed mechanistic investigation of the reaction on the catalyst surface, backed by DFT computational studies, to understand the superior catalytic activity of manganese oxides.
Mechanistic studies of thiourea-catalyzed cross-dehydrogenative C-P and C-C coupling reactions and their further applications
Zhang, Zhiguo,Gu, Kai,Bao, Zongbi,Xing, Huabin,Yang, Qiwei,Ren, Qilong
supporting information, p. 3118 - 3124 (2017/05/08)
Thiourea-based hydrogen bond donor has been recently disclosed by our group to be an efficient organocatalyst for cross-dehydrogenative coupling (CDC) reactions. Here we present a detailed mechanistic study of this reaction using NMR spectroscopy and kine
A comparative mechanistic study of Cu-catalyzed oxidative coupling reactions with N-phenyltetrahydroisoquinoline
Boess, Esther,Schmitz, Corinna,Klussmann, Martin
experimental part, p. 5317 - 5325 (2012/05/05)
A comparative mechanistic study of Cu-catalyzed oxidative coupling reactions of N-phenyltetrahydroisoquinoline with different nucleophiles was conducted. Two previously reported combinations of catalyst and oxidant were studied, CuCl22H2/
