136116-43-3Relevant academic research and scientific papers
Bistriphenylsilanol-assisted oxidation catalyzed by chromium(VI) oxide of activated trimethyl ethers with tert-butyl hydroperoxide
Muzart,N'Ait Ajjou
, p. 1993 - 1996 (1992)
Secondary benzylic or allylic trimetylsilyl ethers are oxidized at room temperature to the corresponding ketones in good yields using aqueous 70% t-BuOOH and catalytic amounts of a mixture of Ph3SiOH and CrO3.
Ketide compounds, method for manufacturing, and use for treating diabetes thereof
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Paragraph 0078; 0178-0181; 0255-0257, (2019/08/27)
The present invention relates to ketide compounds, as well as ketide compounds. The present invention relates to a method for preparing a ketide compound, and a use thereof, in which various anti-diabetic TMPA derivative designs can be induced, and is effective in comparison with existing multi-stage synthesis. In addition, the ketide compounds according to the present invention have strong AMPMPK activity and are expected to be useful as a therapeutic agent for diabetes. (by machine translation)
Highly efficient chromium-catalyzed oxidation of secondary benzylic alcohols by aqueous 70% tert-butyl hydroperoxide
Muzart,N'Ait Ajjou
, p. 785 - 787 (2007/10/02)
The oxidation of secondary benzylic alcohols to ketones by the chromium(VI) oxide/tert-butyl hydroperoxide system is compatible with the presence of methyl, halide, methoxy, acetoxy or nitro substituents on the aryl group and of an unsaturation on the alkyl side chain. Benzyl alcohol led to a mixture of benzaldehyde and benzoic acid.
