Bistriphenylsilanol-assisted oxidation catalyzed by chromium(VI) oxide of activated trimethyl ethers with tert-butyl hydroperoxide

Article abstract of DOI:10.1080/00397919208021332

Secondary benzylic or allylic trimetylsilyl ethers are oxidized at room temperature to the corresponding ketones in good yields using aqueous 70% t-BuOOH and catalytic amounts of a mixture of Ph₃SiOH and CrO₃.

Full text of DOI:10.1080/00397919208021332

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Synthetic Communications: An
International Journal for Rapid
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Organic Chemistry
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Bistriphenylsilanol-Assisted
Oxidation Catalyzed by
Chromium(VI) Oxide of
Activated Trimethylsilyl Ethers
with tert-Butyl Hydroperoxide
Jacques Muzart a & Abdelaziz N'Ait Ajjou a
a Unité de Recherche “Réarrangements Thermiques
et Photochimiques” Associée au C.N.R.S, Université
de Reims Champagne-Ardenne , B.P. 347, 51062,
Reims Cedex, France
Published online: 23 Sep 2006.
To cite this article: Jacques Muzart & Abdelaziz N'Ait Ajjou (1992) Bistriphenylsilanol-
Assisted Oxidation Catalyzed by Chromium(VI) Oxide of Activated Trimethylsilyl Ethers
with tert-Butyl Hydroperoxide, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 22:14, 1993-1996, DOI:
10.1080/00397919208021332
To link to this article: http://dx.doi.org/10.1080/00397919208021332
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