1361325-93-0Relevant academic research and scientific papers
Efficient and Enantioselective Rhodium(I)-Catalyzed Arylation of α-Ketoesters: Synthesis of (S)-Flutriafol
Chang, Chiung-An,Uang, Tsung-Ying,Jian, Jia-Hong,Zhou, Meng-Yi,Chen, Ming-Liang,Kuo, Ting-Shen,Wu, Ping-Yu,Wu, Hsyueh-Liang
supporting information, p. 3381 - 3390 (2018/08/06)
An enantioselective addition of arylboronic acids and α-ketoesters promoted by a Rhodium(I)-chiral diene catalyst is reported. The transformation proceeds regioselectively in the presence of as low as 0.5 mol% of the catalyst generated in situ from a Rhod
Rhodium-catalyzed, highly enantioselective 1,2-addition of aryl boronic acids to α-ketoesters and α-diketones using simple, chiral sulfur-olefin ligands
Zhu, Ting-Shun,Jin, Shen-Shuang,Xu, Ming-Hua
scheme or table, p. 780 - 783 (2012/02/06)
Simply the best: The title reaction has been achieved by asymmetric rhodium catalysis employing an extremely simple, chiral N-(sulfinyl)cinnamylamine ligand. A variety of highly enantioenriched, tertiary α-hydroxy carbonyl derivatives were easily accessed
