1361346-23-7

Basic information

• Product Name: [2,6-[(CH₃)C=N(C₆H₃-2,6-iPr₂)₂]-C₅H₃NSnCl]*[SnCl₃]
• Synonyms: [2,6-[(CH₃)C=N(C₆H₃-2,6-iPr₂)₂]-C₅H₃NSnCl]*[SnCl₃]
• CAS NO: 1361346-23-7
• Molecular Weight: 860.957
• Mol File: 1361346-23-7.mol

Chemical Properties

• CAS DataBase Reference: [2,6-[(CH₃)C=N(C₆H₃-2,6-iPr₂)₂]-C₅H₃NSnCl]*[SnCl₃](CAS DataBase Reference)
• NIST Chemistry Reference: [2,6-[(CH₃)C=N(C₆H₃-2,6-iPr₂)₂]-C₅H₃NSnCl]*[SnCl₃](1361346-23-7)
• EPA Substance Registry System: [2,6-[(CH₃)C=N(C₆H₃-2,6-iPr₂)₂]-C₅H₃NSnCl]*[SnCl₃](1361346-23-7)

Safety Data

• Hazardous Substances Data: 1361346-23-7(Hazardous Substances Data)

Upstream product

• 204203-14-5 N-(2,6-diisopropylphenyl)-N-((1E)-1-(6-[(1E)-N-(2,6-diisopropylphenyl)ethanimidoyl]pyridin-2-yl)ethylidene)amine 

Relevant articles and documents

Lewis base mediated autoionization of GeCl2 and SnCl2

Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets in main group chemistry due to their synthetic potential and industrial applications. In the present study, we describe the synthesis of cationic (MCl+) and anionic (MCl3-) species of heavier low-valent group 14 elements of germanium(II) and tin(II) by using the substituted Schiff base 2,6-diacetylpyridinebis(2,6-diisopropylanil) as Lewis base (LB). Treatment of LB with 2 equiv of GeCl2·dioxane and SnCl2 in toluene gives compounds [(LB)GeIICl] +[GeIICl3]- (1) and [(LB)Sn IICl]+[SnIICl3]- (2), respectively, which possess each a low-valent cation and an anion. Compounds 1 and 2 are well characterized with various spectroscopic methods and single crystal X-ray structural analysis.