1361384-69-1

Basic information

• Product Name: RuCl₂(PPh₃)((R,R)-Me-BIPAM)
• CAS NO: 1361384-69-1
• Molecular Weight: 1195.03
• Mol File: 1361384-69-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: RuCl₂(PPh₃)((R,R)-Me-BIPAM)(CAS DataBase Reference)
• NIST Chemistry Reference: RuCl₂(PPh₃)((R,R)-Me-BIPAM)(1361384-69-1)
• EPA Substance Registry System: RuCl₂(PPh₃)((R,R)-Me-BIPAM)(1361384-69-1)

Safety Data

• Hazardous Substances Data: 1361384-69-1(Hazardous Substances Data)

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 869492-11-5 (R,R)-Me-BIPAM 

Relevant articles and documents

Asymmetric addition of arylboronic acids to glyoxylate catalyzed by a ruthenium/Me-BIPAM complex

The enantioselective synthesis of α-hydroxy esters by ruthenium-catalyzed 1,2-addition of arylboronic acids to tert-butyl glyoxylate is described. The use of RuCl2(PPh3)3 with (R,R)-Me-BIPAM gave optically active mandelic acids of up to 99% ee. Addition of a fluoride salt such as potassium fluoride (KF) or caesium fluoride (CsF) was effective for achieving high enantioselectivities. The Royal Society of Chemistry 2012.