1361387-79-2

Upstream product

• 33652-67-4 (E)-<(E)-benzylideneacetone> oxime O-methyl ether 
• 1361387-25-8 (1E,3E)-5-hydroxy-6-methyl-1-phenylhept-1-en-3-one O-methyl oxime 
• 1361387-53-2 (5E, 6E)-5-(methoxyimino)-2-methyl-7-phenylhept-6-en-3-one 

Downstream Products

• 1361386-96-0 (E)-methyl 2-isopropyl-3-styryl-2H-azirine-2-carboxylate 

Relevant academic research and scientific papers

METHOD FOR PREPARING 2H-AZIRINE CARBOXYLIC ESTERS

The invention relates to a method for preparing 2H-azirine carboxylic esters. More specifically, the invention relates to a method for preparing 2H-azirine carboxylic esters starting from α-diazo-β-keto oxime ethers in the presence of a rhodium (II)-based

Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers

An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields.