33652-67-4Relevant academic research and scientific papers
Reaction of dibenzylphosphine oxide with α,β-unsaturated O-methyloximes
Kolesnik,Tkachev
, p. 624 - 629 (2007/10/03)
The reaction of dibenzylphosphine oxide with O-methyloximes of some α,β-unsaturated ketones results in the phosphorylation at the β-carbon atom to form methoxyiminophosphine oxides, whereas the reaction of dibenzylphosphine oxide with O-methyloximes of α,β-unsaturated aldehydes affords aminodihydrophosphole oxides.
Photochemistry of the Carbon-Nitrogen Double Bond. Part 1. Carbon-Nitrogen vs. Carbon-Carbon Double Bond Isomerisation in the Photochemistry of α,β-Unsaturated Oxime Ethers: The Benzylideneacetone Oxime O-Methyl Ether System
Pratt, Albert C.,Abdul-Majid, Qais
, p. 1691 - 1694 (2007/10/02)
The syntheses of the four benzylideneacetone oxime O-methyl ether isomers (2)-(5) are described.Direct or sensitised irradiation of the E,E-isomer (2) or Z,E-isomer (3) leads to equilibration of all four isomers by a combination of rapid carbon-nitrogen double bond isomerisation and slower carbon-carbon double bond isomerisation.A previous investigation of the photochemistry of the E,E-isomer (2) had reported only carbon-carbon double bond isomerisation.
