1361387-96-3Relevant articles and documents
Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers
Jiang, Yaojia,Chan, Wei Chuen,Park, Cheol-Min
, p. 4104 - 4107 (2012/04/10)
An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields.