13615-35-5

Basic information

• Product Name: AcetaMide, N-(2-Methyl-1-naphthalenyl)-
• Synonyms: AcetaMide, N-(2-Methyl-1-naphthalenyl)-;N-(2-methylnaphthalen-1-yl)acetamide;N-(2-methyl-1-naphthalenyl)acetamide
• CAS NO: 13615-35-5
• Molecular Formula: C13H13NO
• Molecular Weight: 199.24842
• Mol File: 13615-35-5.mol
• Article Data: 6

Chemical Properties

• Melting Point: 188 °C
• Boiling Point: 397.5±11.0 °C(Predicted)
• Appearance: /
• Density: 1.152±0.06 g/cm3(Predicted)
• Storage Temp.: 2-8°C
• PKA: 15.45±0.43(Predicted)
• CAS DataBase Reference: AcetaMide, N-(2-Methyl-1-naphthalenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: AcetaMide, N-(2-Methyl-1-naphthalenyl)-(13615-35-5)
• EPA Substance Registry System: AcetaMide, N-(2-Methyl-1-naphthalenyl)-(13615-35-5)

Safety Data

• Hazardous Substances Data: 13615-35-5(Hazardous Substances Data)

Usage

Description

Acetamide, N-(2-methyl-1-naphthalenyl)-, also known as N-(2-Methylnaphthalen-1-yl)acetamide, is a chemical compound derived from 1-Naphthaleneacetamide, a plant rooting hormone. It is a derivative of 1-Acetamidonaphthalene (A158455), which is a protected Naphthylamine. Acetamide, N-(2-methyl-1-naphthalenyl)is characterized by its unique molecular structure and potential applications in various fields.

Uses

Used in Plant Growth Regulation:
Acetamide, N-(2-methyl-1-naphthalenyl)-, is used as a growth regulator in the agricultural industry for its ability to influence plant growth and development. As an impurity of the plant rooting hormone 1-Naphthaleneacetamide, it plays a role in enhancing root growth and overall plant health.
Used in Chemical Synthesis:
In the chemical industry, Acetamide, N-(2-methyl-1-naphthalenyl)is used as an intermediate in the synthesis of various compounds, including pharmaceuticals and other specialty chemicals. Its unique structure makes it a valuable building block for creating novel molecules with potential applications in different sectors.
Used in Research and Development:
Acetamide, N-(2-methyl-1-naphthalenyl)is also utilized in research and development for studying the properties and behavior of naphthalene-based compounds. Its role in understanding the structure-activity relationships of related molecules can contribute to the discovery of new compounds with specific applications in various industries.

Upstream product

• 2246-44-8 1-amino-2-methylnaphthalene 
• 108-24-7 acetic anhydride 
• 881-03-8 1-nitro-2-methylnaphthalene 
• 98154-51-9 1-azido-2-methylnaphthalene 
• 10387-40-3 potassium thioacetate 
• 110678-73-4 1-(2-methyl-1-naphthyl)-4,5-bis(trimethylsilyl)-1,2,3-triazole 
• 106469-17-4 N-(2-Methyl-1,4-dihydro-naphthalen-1-yl)-acetamide 

Downstream Products

• 83-68-1 2-methyl-naphthalene-1,4-diyldiamine 
• 50870-10-5 3-methyl-[1]naphthylamine 
• 13615-38-8 2-methyl-4-nitronaphthalene 
• 13615-40-2 3-methylnaphthalen-1-ol 
• 5465-56-5 4-nitro-2-methyl-[1]naphthylamine 
• 13615-36-6 1-Acetylamino-2-methyl-4-nitro-naphthalin 

Relevant articles and documents

Methylterrylene isomers

2-Methyl and 3-methylterrylenes have been obtained by Suzuki coupling of 3-bromoperylene and corresponding methylnaphthylboronic acids or esters, giving methylnaphthylperylene isomers, followed by Scholl cyclodehydrogenation; the latter reaction gave also the other cyclodehydrogenation isomers 10- (respectively, 9-) methylbenzo[4,5]indeno[1,2,3-cd]perylene.

ONE-POT REDUCTIVE ACETAMIDATION OF ARYL NITRO COMPOUNDS

The present invention provides a method for the reductive acetamidation of an aryl nitro compound by reacting a substituted acid with an aryl nitro compound and adding a catalytic amount of a base with the substituted acid and the aryl nitro compound to form an acetamidation aryl nitro compound. The acetamidation aryl nitro compound is then purified.

Photolysis of 1-Aryl-1,2,3-triazoles; Rearrangement via !H-Azirines

The preparation and photolysis of a series of 1-(1-naphthyl)-1,2,3-triazoles, (2)-(5), and of 1-(2-methyl-1-naphthyl)-1,2,3-triazoles, (6)-(9), with and without electron-withdrawing groups (CO2R, CONH2, CN, CHO, COPh) in the triazole ring, are described.In the first series, triazoles (3) with two electron-withdrawing groups, and triazoles (4) with one such group at C-4, mostly give good yields of the expected benzindoles (10) and 11 respectively.Triazoles (5) with the electron-withdrawing group at C-5 also give benzindoles but these are now mixtures of the expected (12) and rearranged indoles (11).Photolysis of the 1-phenyltriazoles (21) and (22) follows the same pattern, those with the electron-withdrawing group at C-5 rearranging to give mixtures of indoles (23) and (24).This is explained by a mechanism (Scheme 3) in which the less stable carbene intermediate (13) rearranges to the more stable carbene (15) via the 1H-azirine (14), in competition with its direct cyclisation.This provides the first evidence for antiaromatic 1H-azirines as intermediates in a photochemical reaction.Photolysis of the 2-methylnaphthyl compounds follows a different path: diester (7b) and dinitrile (7d) give high yields of the deeply coloured 9-methyl-1H-benzoquinoline derivatives (25a) and (25b) respectively, the first stable examples of this ring system to be isolated.Photolysis of the nitrile (8c) gives 9b-methyl-9bH-benzindole-3-carbonitrile (28), a rare example of a stable indole with a ring junction substituent. 1,2-Shifts in the carbenes are only observed with the bis(trimethylsilyl)triazoles (2d) and (6f), in keeping with the known rapid migration of trimethylsilyl groups to carbene centres.