136174-88-4Relevant academic research and scientific papers
Reagent-Controlled Stereoselective Glycosylation
-
Paragraph 0196; 0197; 0198; 0199; 0200; 0201; 0202, (2015/02/19)
Provided are methods for the efficient stereoselective formation of glycosidic bonds, without recourse to prosthetic or directing groups.
Reagent controlled β-specific dehydrative glycosylation reactions with 2-deoxy-sugars
Issa, John Paul,Lloyd, Dina,Steliotes, Emily,Bennett, Clay S.
supporting information, p. 4170 - 4173 (2013/09/12)
N-Sulfonyl imidazoles activate 2-deoxy-sugar hemiacetals for glycosylation presumably by converting them into glycosyl sulfonates in situ. By matching the leaving group ability of the sulfonate with the reactivity of the donor, it is possible to obtain β-
Studies on the synthesis of aureolic acid antibiotics: Highly stereoselective synthesis of aryl 2-deoxy-β-glycosides via the Mitsunobu reaction and synthesis of the olivomycin A-B disaccharide
Roush, William R.,Lin, Xiao-Fa
, p. 2236 - 2250 (2007/10/02)
The Mitsunobu reaction of phenols and 1,2-cis-2-thiophenyl-α-D-glycopyranoses or 1,2-cis-2-selenophenyl-α-D-glycopyranoses is a very effective method for the highly stereoselective synthesis of aryl 2-deoxy-β-D-glycosides. The equatorial 2-thiophenyl or 2
