1362132-11-3

Basic information

• Product Name: (R)-1-(4-methoxyphenyl)-1,2,3,4-tetrahydronaphthalen-1-ol
• Synonyms: (R)-1-(4-methoxyphenyl)-1,2,3,4-tetrahydronaphthalen-1-ol
• CAS NO: 1362132-11-3
• Molecular Weight: 254.329
• Mol File: 1362132-11-3.mol

Chemical Properties

• CAS DataBase Reference: (R)-1-(4-methoxyphenyl)-1,2,3,4-tetrahydronaphthalen-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-(4-methoxyphenyl)-1,2,3,4-tetrahydronaphthalen-1-ol(1362132-11-3)
• EPA Substance Registry System: (R)-1-(4-methoxyphenyl)-1,2,3,4-tetrahydronaphthalen-1-ol(1362132-11-3)

Safety Data

• Hazardous Substances Data: 1362132-11-3(Hazardous Substances Data)

Upstream product

• 7294-51-1 2,4,6-tris(4-methoxyphenyl)boroxine 
• 5720-07-0 4-methoxyphenylboronic acid 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 

Relevant articles and documents

Chromium(II)-catalyzed enantioselective arylation of ketones

The chromium-catalyzed enantioselective addition of carbo halides to carbonyl compounds is an important transformation in organic synthesis. However, the corresponding catalytic enantioselective arylation of ketones has not been reported to date. Herein, we report the first Cr-catalyzed enantioselective addition of aryl halides to both arylaliphatic and aliphatic ketones with high enantioselectivity in an intramolecular version, providing facile access to enantiopure tetrahydronaphthalen-1-ols and 2,3-dihydro-1H-inden-1-ols containing a tertiary alcohol.

Rhodium(I)/diene-catalyzed addition reactions of arylborons with ketones

Rh(I)/diene-catalyzed addition reactions of arylboroxines/arylboronic acids with unactivated ketones to form tertiary alcohols in good to excellent yields are described. By using C2-symmetric (3aR,6aR)-3,6-diaryl-1,3a,4,6a- tetrahydropentalenes as ligands, the asymmetric version of such an addition reaction, with up to 68% ee, was also realized.