13622-77-0Relevant academic research and scientific papers
Communication of electronic information over nanometer distances with supramolecular transduction. An experimental and density functional investigation
Deans, Robert,Cuello, Alejandro O.,Galow, Trent H.,Ober, Matthias,Rotello, Vincent M.
, p. 1309 - 1313 (2007/10/03)
We have synthesized a family of conjugated diaminotriazine-functionalized receptors. Variation of distal functionality modulated the affinity of these receptors for flavin, demonstrating efficient electronic communication over a distance of 11 A. The origin of this communication was explored using DFT methodology. These calculations demonstrate that modulation of recognition in these systems is derived from a complex push-pull type mechanism.
