13625-35-9

Basic information

• Product Name: 2-[(4-chlorophenyl)amino]benzonitrile
• Synonyms: 2-[(4-chlorophenyl)amino]benzonitrile
• CAS NO: 13625-35-9
• Molecular Weight: 228.681
• Mol File: 13625-35-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-[(4-chlorophenyl)amino]benzonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(4-chlorophenyl)amino]benzonitrile(13625-35-9)
• EPA Substance Registry System: 2-[(4-chlorophenyl)amino]benzonitrile(13625-35-9)

Safety Data

• Hazardous Substances Data: 13625-35-9(Hazardous Substances Data)

Upstream product

• 55305-43-6 N-cyano-N-phenyl-p-toluenesulfonamide 
• 100124-46-7 (4-chloro-phenyl)-nitroso-phenyl-amine 
• 13463-94-0 N-(4-chlorophenyl)cyanamide 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 106-47-8 4-chloro-aniline 
• 17264-73-2 sodium o-bromobenzoate 
• 13278-35-8 2-(4-chloroanilino)benzoic acid 
• 13799-33-2 2-((4-chlorophenyl)amino)benzamide 

Downstream Products

• 95888-31-6 2-chloro-10-phenylacridine 

Relevant articles and documents

Rhodium(III)-Catalyzed Direct Cyanation of Aromatic C-H Bond to Form 2-(Alkylamino)benzonitriles Using N-Nitroso As Directing Group

2-(Alkylamino)benzonitriles were synthesized via a rhodium-catalyzed cyanation on the aryl C-H bond and subsequent denitrosation of N-nitrosoarylamines using a removable nitroso as the directing group, in which N-cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS) was used as the "CN" source. Various substituents on the aryl ring and amino group of N-nitrosoarylamines tolerated the reaction, and the corresponding products were achieved in moderate to good yields.