13629-88-4Relevant academic research and scientific papers
Atom-efficient Pd-catalyzed cross-couplings of chloroarenes with triarylbismuth reagents
Rao, Maddali L.N.,Meka, Suresh
supporting information, (2019/07/30)
Various Pd-catalyzed protocols have been developed for the atom-efficient cross-coupling of chloroarenes with triarylbismuth reagents. Using the developed protocols, an efficient synthesis of unsymmetrical biaryls in good to excellent yields was achieved by employing electron-deficient chloroarenes and a range of triarylbismuth reagents.
Suzuki-Miyaura reaction of chloroarenes using Pd(PPh3) 4 as catalyst
Thiemann, Thies,Tanaka, Yasuko,Hisaindee, Soleiman,Kaabi, Maitha
experimental part, p. 34 - 38 (2010/06/16)
The reactivity of a number of chloroarenes was investigated and chloro-nitroarenes were found to undergo facile arylation with Pd(PPh 3)4 / [Pd(PPh3)2Cl 2/n.PPh3] as catalyst. Furthermore, 4-chlorobenzaldehyde underwent arylation under the conditions, albeit with a higher catalyst loading.
