13630-61-0

Basic information

• Product Name: 3-(2,2-Dichlorophenyl)-2,2-dimethylcyclopropanecarbonyl chloride (control hydrochloride)
• Synonyms: 3-(2,2-Dichlorophenyl)-2,2-dimethylcyclopropanecarbonyl chloride (control hydrochloride);4-Trichloromethyl-4-methyl-2,5-cyclohexadien-1-ol
• CAS NO: 13630-61-0
• Molecular Formula: C₈H₉Cl₃O
• Molecular Weight: 227.52
• Mol File: 13630-61-0.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 291.5°Cat760mmHg
• Flash Point: 130.1°C
• Appearance: /
• Density: 1.427g/cm³
• Vapor Pressure: 0.000209mmHg at 25°C
• Refractive Index: 1.565
• CAS DataBase Reference: 3-(2,2-Dichlorophenyl)-2,2-dimethylcyclopropanecarbonyl chloride (control hydrochloride)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2,2-Dichlorophenyl)-2,2-dimethylcyclopropanecarbonyl chloride (control hydrochloride)(13630-61-0)
• EPA Substance Registry System: 3-(2,2-Dichlorophenyl)-2,2-dimethylcyclopropanecarbonyl chloride (control hydrochloride)(13630-61-0)

Safety Data

• Hazardous Substances Data: 13630-61-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H9Cl3O/c1-7(8(9,10)11)4-2-6(12)3-5-7/h2-6,12H,1H3

Upstream product

• 3274-12-2 4-methyl-4-(trichloromethyl)cyclohexa-2,5-dien-1-one 

Downstream Products

• 13630-17-6 1-Chlor-4-methyl-4-trichlormethyl-cyclohexadien-(2,5) 
• 3335-33-9 1-methyl-2-trichloromethyl-benzene 
• 118-90-1 ortho-methylbenzoic acid 

Relevant articles and documents

Toluene as a novel carrier of xanthates - Preparation, use and surrogate of S-tri- and di-chloromethyl xanthates

Toluene has been identified as a novel carrier of xanthates. Their corresponding fragmentative precursors proved to behave efficiently in radical group transfer reactions. As examples, unprecedented S-tri/di-chloromethyl xanthates could be prepared, isolated and further used in radical additions to olefins. Their precursors (de-aromatized toluene upon which is grafted, at one end, a tri/di-chloromethyl-group and, at the other end, a dithiocarbonyl group) can also be used directly in the transfer of both groups to olefins. The re-aromatizing loss of toluene by radical initiated fragmentation of the precursors brings thus new opportunities to the chemistry of xanthates, exemplified here in the intermolecular additions to olefins of new S-tri/di-chloromethyl xanthates.