136346-86-6Relevant academic research and scientific papers
NHC-Copper(I) Halide-Catalyzed Direct Alkynylation of Trifluoromethyl Ketones on Water
Czerwiński, Pawe?,Molga, Edyta,Cavallo, Luigi,Poater, Albert,Michalak, Micha?
supporting information, p. 8089 - 8094 (2016/06/13)
An efficient and easily scalable NHC-copper(I) halide-catalyzed addition of terminal alkynes to 1,1,1-trifluoromethyl ketones, carried out on water for the first time, is reported. A series of addition reactions were performed with as little as 0.1-2.0?mo
SYNTHESIS OF FUNCTIONALLY SUBSTITUTED ALCOHOLS CONTAINING A CF3 GROUP BY THE CONDENSATION OF ARYL AND HETEROARYL TRIFLUOROMETHYL KETONES WITH CH ACIDS
Moskalev, N. V.,Filimonov, V. D.,Timoshchenko, L. V.
, p. 1902 - 1904 (2007/10/02)
The respective trifluoromethylcarbinols were obtained by the condensation of p-(trifluoroacetyl)-N,N-dimethylaniline or 9-methyl-3-trifluoroacetylcarbazole with a series of CH acids in the presence of potassium tert-butoxide, butyllithium, or KF-Al6O3.
