136353-60-1

Basic information

• Product Name: 5-deoxy-1,2-O-isopropylidene-3-O-p-nitrobenzoyl-α-D-xylofuranose
• Synonyms: 5-deoxy-1,2-O-isopropylidene-3-O-p-nitrobenzoyl-α-D-xylofuranose
• CAS NO: 136353-60-1
• Molecular Weight: 323.302
• Mol File: 136353-60-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-deoxy-1,2-O-isopropylidene-3-O-p-nitrobenzoyl-α-D-xylofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 5-deoxy-1,2-O-isopropylidene-3-O-p-nitrobenzoyl-α-D-xylofuranose(136353-60-1)
• EPA Substance Registry System: 5-deoxy-1,2-O-isopropylidene-3-O-p-nitrobenzoyl-α-D-xylofuranose(136353-60-1)

Safety Data

• Hazardous Substances Data: 136353-60-1(Hazardous Substances Data)

Upstream product

• 6893-65-8 1,2-di-O-isopropylidene-5-O-tosyl-D-xylofuranose 
• 122-04-3 4-nitro-benzoyl chloride 
• 4152-79-8 1,2-O-isopropylidene-5-methyl-5-deoxy-α-D-xylofuranose 

Downstream Products

• 136353-67-8 methyl 5-deoxy-2-O-mesyl-3-O-p-nitrobenzoyloxy-α,β-D-xylofuranoside 
• 136353-64-5 5-deoxy-2-O-mesyl-3-O-p-nitrobenzoyloxy-α,β-D-xylofuranose 
• 136353-66-7 (+)-(3R,4S,5R)-3-mesyloxy-5-methyl-4-p-nitrobenzoyloxy-dihydro-2(3H)-furanone 
• 136353-57-6 4-Nitro-benzoic acid (2R,3R,4R)-4-hydroxy-5-methoxy-2-methyl-tetrahydro-furan-3-yl ester 
• 136353-61-2 (+)-(3R,4S,5R)-3-hydroxy-4-p-nitrobenzoyloxy-5-methyldihydro-2(3H)-furanone 

Relevant articles and documents

Practical synthesis of optically pure 3,4-epoxy-5-methyldihydro-2(3H)-furanones from D-xylose by regio- and stereo-selective functionalization

The known 1,2-O-isopropylidene-5-O-p-tolylsulfonyl-α-D-xylofuranose was converted into its 3-p-nitrobenzoate (13a) and 3-methanesulfonate (13b). (-)-(3S,4S,5R)-3,4-Epoxy-5-methyldihydro-2(3H)-furanone was synthesized from 13a in 5 steps by convers