136367-87-8Relevant academic research and scientific papers
Catalytic ring-opening allylation of cyclic acetals with allylsilanes using silica-alumina
Motokura, Ken,Yoneda, Hirokazu,Miyaji, Akimitsu,Baba, Toshihide
supporting information; experimental part, p. 1373 - 1375 (2010/09/08)
Ring-opening allylation of cyclic acetals has required stoichiometric amounts of Lewis acids. In this paper, catalytic ring-opening allylation in the presence of silica-alumina is reported. This ring-opening allylation showed high atom economy. Consecutiv
"Cation pool" method based on C-C bond dissociation. Effective generation of monocations and dications
Okajima, Masayuki,Suga, Seiji,Itami, Kenichiro,Yoshida, Jun-Ichi
, p. 6930 - 6931 (2007/10/03)
The "cation pools" of alkoxyarylcarbenium ions were effectively generated by the oxidative C-C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles. Copyright
REACTIONS OF 1,3-DIOXACYCLOALKANES WITH TRIMETHYLPROPENYLSILANE
Mikhailova, I. Yu.,Mel'nitskii, I. A.,Kuladze, T. K.,Kantor, E. A.
, p. 710 - 713 (2007/10/02)
5-Oxa-8-trimethylsilyloxyoctenes are formed during the cleavage of 1,3-dioxacycloalkanes with trimethylpropenylsilane in the presence of metal halides.The use of boron trifluoride etherate changes the direction of the process and lead to the diallyl ether
