936-51-6

Basic information

• Product Name: 2-PHENYL-1,3-DIOXOLANE
• Synonyms: LABOTEST-BB LT02097925;2-PHENYL-1,3-DIOXOLANE;RARECHEM AL BP 0531;Benzaldehyde ethylene acetal;1-(1,3-Dioxolane-2-yl)benzene;Benzaldehyde (ethane-1,2-diyl)acetal
• CAS NO: 936-51-6
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.17
• EINECS: 213-315-5
• Product Categories: Acetals/Ketals/Ortho Esters;Organic Building Blocks;Oxygen Compounds
• Mol File: 936-51-6.mol
• Article Data: 135

Chemical Properties

• Boiling Point: 80 °C0.3 mm Hg(lit.)
• Flash Point: 209 °F
• Appearance: /
• Density: 1.106 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0808mmHg at 25°C
• Refractive Index: n20/D 1.526(lit.)
• CAS DataBase Reference: 2-PHENYL-1,3-DIOXOLANE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-PHENYL-1,3-DIOXOLANE(936-51-6)
• EPA Substance Registry System: 2-PHENYL-1,3-DIOXOLANE(936-51-6)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 936-51-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 438, 1978 DOI: 10.1021/jo00397a013Synthesis, p. 808, 1974 DOI: 10.1055/s-1974-23438Tetrahedron Letters, 32, p. 5667, 1991 DOI: 10.1016/S0040-4039(00)93524-X

InChI:InChI=1/C9H10O2/c1-2-4-8(5-3-1)9-10-6-7-11-9/h1-5,9H,6-7H2

Upstream product

• 100-52-7 benzaldehyde 
• 107-21-1 ethylene glycol 
• 17789-14-9 3-(1,3-dioxolan-2-yl)-phenylbromide 
• 19158-51-1 P-toluenesulfonyl cyanide 
• 120-92-3 cyclopentanone 
• 111-90-0 ethoxyethoxyethanol 
• 4460-46-2 3-chloro-3-phenyl-3H-diazirine 
• 110-80-5 2-ethoxy-ethanol 
• 74733-97-4 2-<2-(2-<2-(2-methoxyethoxy)ethoxy>ethoxy)ethoxy>-1,3-dioxolan 
• 74733-98-5 2-(2-<2-(2-methoxyethoxy)ethoxy>ethoxy)-1,3-dioxolan 
• 74733-99-6 2-<2-(2-methoxyethoxy)ethoxy>-1,3-dioxolan 
• 28104-05-4 2-(2-methoxyethoxy)-1,3-dioxolan 
• 132636-67-0 3-(4-[1,3]Dioxolan-2-yl-phenoxy)-benzo[d]isothiazole 1,1-dioxide 
• 81381-75-1 1,3-Bis(1,3-dioxan-2-yloxy)propane 

Downstream Products

• 80378-34-3 3-phenyl-[1,4]dioxanecarboxylic acid ethyl ester 
• 939-54-8 2-bromoethyl benzoate 
• 4353-40-6 2-phenyl-[1,3]dioxolan-2-yl hydroperoxide 
• 622-08-2 2-Benzyloxyethanol 
• 56849-47-9 4-(β-Hydroxyethoxy)-4-phenylbut-2-in 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 3418-37-9 2-phenyl-2-phenylchloromethyl-1,3-dioxolane 
• 94-49-5 1,2-ethanediol, dibenzoate 
• 94-50-8 n-octyl benzoate 
• 6853-01-6 2-phenylcyclopentane-1,3-dione 
• 927-68-4 bromoethyl acetate 
• 100-52-7 benzaldehyde 
• 59258-76-3 2-chloromethyl-2-phenyl-1,3-dioxolane 
• 7315-50-6 α,α-bis(butylthio)toluene 

Relevant articles and documents

Synthesis of novel acidic ionic liquid immobilized on silica

A novel acidic ionic liquid immobilized on silica has been synthesized by hydrolyzing tetraethyl orthosilicate (TEOS) and the acidic ionic liquid derived from (3-aminopropyl) trimethoxysilane. The catalytic activities were evaluated in the acetalization a

Ultrafast and continuous synthesis of unaccommodating inorganic nanomaterials in droplet- and ionic liquid-assisted microfluidic system

Despite many efforts on the synthesis of inorganic nanomaterials with uniform structure and narrow size distribution in a fast and continuous way, it is still a critical challenge in the chemistry research community due to the uncontrollable mass and heat

Application of poly(Vinylbenzyltrimethylammonium tribromide) resin as an efficient polymeric catalyst in the acetalization and diacetylation of benzaldehydes

The applications of a new supported tribromide reagent (poly(vinylbenzyltrimethylammonium tribromide) resin) were reported. This supported tribromide resin was used as a catalyst in the acetalization and diacetylation of benzaldehydes under mild conditions with high efficiency. The effects of solvents, and amount of the supported tribromide resin on the reactions were investigated. Under the optimal conditions, most of acetal and 1,1-diacetates of benzaldehydes were selectively obtained in excellent yields.

Highly selective reductive catalytic fractionation at atmospheric pressure without hydrogen

Reductive catalytic fractionation (RCF) is an efficient and selective way to produce phenolic monomers from lignin. However, this strategy is difficult to scale up due to its high operating pressure. In this work, we investigated RCF reaction at or near atmospheric pressure and without the use of hydrogen. The atmospheric RCF (ARCF) was conducted in acidified ethylene glycol in glass vessels at 185-195 °C catalyzed by 5% Ru/C. The products mainly include propylguaiacol and propylsyringyl (up to 95.6% among the lignin monomers) and do not contain propanolguaiacol, propanolsyringyl, or H monomers. Although the total yield of lignin monomers in ARCF is about one-quarter less than that of RCF, the operation of ARCF is much easier, milder, safer, and cheaper due to the atmospheric condition and the feasibility of the semi-continuous operation.