136378-30-8Relevant academic research and scientific papers
Palladium-Catalyzed Sulfinylation of Aryl- And Alkenylborons with Sulfinate Esters
Hosoya, Takamitsu,Kanemoto, Kazuya,Nakamura, Yu,Suzuki, Minori,Yoshida, Suguru
supporting information, p. 3793 - 3797 (2021/05/29)
An efficient, direct sulfinylation of organoborons catalyzed by palladium is disclosed. Treatment of organoborons and sulfinate esters in the presence of a palladium precatalyst provided a broad range of sulfoxides. Various organosulfur compounds having oxidizable functional groups were successfully prepared through the sulfoxide synthesis.
Direct S-arylation of unactivated arylsulfoxides using [Pd(IPr*)(cin) Cl]
Izquierdo, Frédéric,Chartoire, Anthony,Nolan, Steven P.
, p. 2190 - 2193 (2013/10/22)
The direct S-arylation of unactivated arylsulfoxides catalyzed by [Pd(IPr*)(cin)Cl] is described. Several arylmethylsulfoxides were coupled to various aryl halides in moderate to good yields (17 examples, 34-85%). Scope, limitations, and reaction mechanis
Aryl sulfoxides from aliyi sulfoxides via [2,3]-sigmatropic rearrangement and domino Pd-catalyzed generation/ arylation of sulfenate anions
Bernoud, Ellse,Le Duc, Gaetan,Bantrell, Xavier,Prestat, Guillaume,Madec, David,Poll, Giovanni
supporting information; experimental part, p. 320 - 323 (2010/03/24)
(Figure presented) Allylic sulfoxides, via [2,3]-sigmatropic rearrangement and oxidative addition of the resulting allylic sulfonate esters to Pd(0), are found to be excellent precursors of sulfenate anions. This hitherto unknown reactivity is applied in a new Pd(0)-catalyzed domino sequence involving sulfonate anion generation followed by arylation to afford aryl sulfoxides.
Use of Carbohydrates in the Preparation of Optically Active Sulphoxides
Ridley, Damon D.,Smal, Mary A.
, p. 505 - 506 (2007/10/02)
The diastereomeric sulphinate esters formed from arenesulphinyl chlorides and 1,2:5,6-di-O-cyclohexylidene-D-glucofuranose afford optically active sulphoxides on treatment with Grignard reagents.
