35330-76-8

Basic information

• Product Name: 2-(Methylsulfinyl)naphthalene ,97%
• Synonyms: 2-(Methylsulfinyl)naphthalene ,97%
• CAS NO: 35330-76-8
• Molecular Formula: C₁₁H₁₀OS
• Molecular Weight: 190
• Mol File: 35330-76-8.mol
• Article Data: 90

Chemical Properties

• Boiling Point: 384.2°C at 760 mmHg
• Flash Point: 186.2°C
• Appearance: /
• Density: 1.25g/cm³
• Vapor Pressure: 9.17E-06mmHg at 25°C
• Refractive Index: 1.69
• CAS DataBase Reference: 2-(Methylsulfinyl)naphthalene ,97%(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Methylsulfinyl)naphthalene ,97%(35330-76-8)
• EPA Substance Registry System: 2-(Methylsulfinyl)naphthalene ,97%(35330-76-8)

Safety Data

• Statements: 22-34
• Safety Statements: 26-36/37/39-35
• Hazardous Substances Data: 35330-76-8(Hazardous Substances Data)

Usage

Chemical Properties

Off-white solid

InChI:InChI=1/C11H10OS/c1-13(12)11-7-6-9-4-2-3-5-10(9)8-11/h2-8H,1H3

Upstream product

• 60142-34-9 2-Bromomethanesulfinyl-naphthalene 
• 7433-79-6 2-methylthionaphthalene 
• 91-60-1 2-Naphthalenethiol 
• 1308834-02-7 2-(2-naphthylsulfanyl)ethyl phenyl sulfone 
• 1308833-67-1 2-(naphthylsulfinyl)ethyl phenyl sulfone 
• 74-88-4 methyl iodide 
• 75-16-1 methylmagnesium bromide 
• 67-68-5 dimethyl sulfoxide 
• 105163-70-0 2-naphthyl 2-(4-pyridyl)ethyl sulfide 
• 134613-51-7 (Z)-2-(2-bromoethenylthio)naphthalene 
• 35330-76-8 (R)-2-naphthyl methyl sulfoxide 
• 138286-19-8 (+)-(Z)-2-(2-bromoethenylsulfinyl)naphthalene 
• 105163-67-5 4-[2-(Naphthalene-2-sulfinyl)-ethyl]-pyridine 

Downstream Products

• 35330-75-7 2-(methylsulfonyl)naphthalene 
• 38226-53-8 1-(Naphthalene-2-sulfinylmethyl)-cyclohexanol 
• 38226-61-8 C₂₆H₂₂O₂S 
• 38226-50-5 1-(4-Dimethylamino-phenyl)-2-(naphthalene-2-sulfinyl)-ethanol 
• 38226-63-0 C₂₇H₂₄O₃S 
• 38226-51-6 2-(4-Methoxy-phenyl)-1-(naphthalene-2-sulfinyl)-propan-2-ol 
• 38226-62-9 C₂₇H₂₄O₂S 
• 38226-60-7 [2-(Naphthalene-2-sulfinyl)-1-phenyl-ethyl]-phenyl-amine 
• 38226-52-7 1-(Naphthalene-2-sulfinyl)-2-phenyl-pentan-2-ol 
• 38306-16-0 4-(Naphthalene-2-sulfinyl)-2,3-diphenyl-butyronitrile 
• 35330-76-8 (R)-2-naphthyl methyl sulfoxide 
• 114129-50-9 (S)-methyl 2-naphthylsulfoxide 
• 1323994-03-1 C₂₀H₁₈O₃S 
• 1323993-91-4 (+/-)-2-[(2-naphthylsulfinyl)methyl]chroman-2-ol 

Relevant articles and documents

2D and 3D Porphyrinic Covalent Organic Frameworks: The Influence of Dimensionality on Functionality

The construction of 2D and 3D covalent organic frameworks (COFs) from functional moieties for desired properties has gained much attention. However, the influence of COFs dimensionality on their functionalities, which can further assist in COF design, has

Extending aromatic acids on TiO2 for cooperative photocatalysis with triethylamine: Violet light-induced selective aerobic oxidation of sulfides

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Organocatalytic sulfoxidation

Treatment of a sulfide with a catalytic amount of a 1,3-diketone in the presence of silica sulfuric acid as a co-catalyst and hydrogen peroxide (50% aq) as the stoichiometric oxidant leads to the corresponding sulfoxide product. The reaction is effective for diaryl, aryl-alkyl and dialkyl sulfides and is tolerant of oxidisable and acid sensitive functional groups. Investigations have shown that the tris-peroxide 2, formed on reaction of pentane-2,4-dione with hydrogen peroxide under acidic reaction conditions, can oxidise two equivalents of sulfide using the exocyclic peroxide groups whereas the endocyclic peroxide remains intact. Calculations provide a mechanism consistent with experimental observations and suggest the reaction proceeds via an initial acid catalysed ring opening of a protonated tris-peroxide prior to oxygen transfer to a sulfur nucleophile.