136386-53-3

Upstream product

• 130703-27-4 methyl 2,3-di-O-benzyl-6-O-tosyl-α-D-galactopyranoside 
• 29388-46-3 methyl 2,3-di-O-benzyl-α-D-galactopyranoside 
• 108-24-7 acetic anhydride 

Downstream Products

• 136458-75-8 2D-(2,3/4,5)-2-O-acetyl-3,4-di-O-benzyl-2,3,4,5-tetrahydroxycyclohexanone 
• 136458-78-1 2D-(2,3,5/4)-2-O-acetyl-3,4-di-O-benzyl-2,3,4,5-tetrahydroxycyclohexanone 
• 136458-76-9 2D-(2,3/4)-2-O-acetyl-3,4-di-O-benzyl-2,3,4-trihydroxy-5-cyclohexen-1-one 
• 136386-48-6 methyl 4-O-acetyl-2,3-di-O-benzyl-6-deoxy-β-L-arabino-hex-5-enopyranoside 

Relevant academic research and scientific papers

Synthesis of Optically Active Substituted Cyclohexenones from Carbohydrates by Catalytic Ferrier Rearrangement

Conversion of hex-5-enopyranosides into substituted cyclohexenones (Ferrier rearrangement) was found to proceed efficiently with a catalytic amount of various mercury(II) salts at room temperature in a neutral solvent system.Among the mercury(II) salts tested, mercury(II) trifluoroacetate showed the highest activity.Four optically active cyclohexenones were prepared from hex-5-enopyranosides utilizing this method.