13639-54-8

Basic information

• Product Name: 1-Thio-beta-D-glucopyranose 2,3,4,6-tetraacetate 1-(O-ethylcarbonodithioate)
• Synonyms: 2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl Ethylxanthogenate;2,3,4,6-Tetra-O-acetyl-β-D-glucose ethylxanthat;1-Thio-beta-D-glucopyranose 2,3,4,6-tetraacetate 1-(O-ethylcarbonodithioate);.beta.-D-Glucopyranose, 1-thio-, 2,3,4,6-tetraacetate 1-(o-ethylcarbonodithioate);Aids080748;Aids-080748;Nsc66060;glucopyranosyl Ethylxanthogenate
• CAS NO: 13639-54-8
• Molecular Formula: C₁₇H₂₄O₁₀S₂
• Molecular Weight: 452.5
• Product Categories: Carbohydrates;Carbohydrates & Derivatives;Sulfur & Selenium Compounds
• Mol File: 13639-54-8.mol
• Article Data: 2

Chemical Properties

• Melting Point: 88-890C
• Boiling Point: 514.3 °C at 760 mmHg
• Flash Point: 264.8 °C
• Appearance: /
• Density: 1.34
• Vapor Pressure: 1.1E-10mmHg at 25°C
• Refractive Index: 1.535
• Storage Temp.: Refrigerator
• Solubility: Chloroform, Ethyl Acetate, Methanol
• CAS DataBase Reference: 1-Thio-beta-D-glucopyranose 2,3,4,6-tetraacetate 1-(O-ethylcarbonodithioate)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Thio-beta-D-glucopyranose 2,3,4,6-tetraacetate 1-(O-ethylcarbonodithioate)(13639-54-8)
• EPA Substance Registry System: 1-Thio-beta-D-glucopyranose 2,3,4,6-tetraacetate 1-(O-ethylcarbonodithioate)(13639-54-8)

Safety Data

• Hazardous Substances Data: 13639-54-8(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

Uses

2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl Ethylxanthate (cas# 13639-54-8) is a compound useful in organic synthesis.

InChI:InChI=1/C17H24O10S2/c1-6-22-17(28)29-16-15(26-11(5)21)14(25-10(4)20)13(24-9(3)19)12(27-16)7-23-8(2)18/h12-16H,6-7H2,1-5H3/t12-,13-,14+,15-,16+/m1/s1

Upstream product

• 140-89-6 potassium ethyl xanthogenate 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 

Downstream Products

• 54497-82-4 S-cyclohexyl O-ethyl carbonodithioate 
• 16750-06-4 1,3,4,6-tetra-O-acetyl-2-deoxy-α-D-arabinohexopyranose 
• 32934-24-0 ethyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 

Relevant articles and documents

A novel approach for the formation of carbon-nitrogen bonds: Azidation of alkyl radicals with sulfonyl azides

Two preparatively attractive methods for the azidation of alkyl radicals are described. Secondary and tertiary alkyl iodides and dithiocarbonates are easily converted into the corresponding azides, either by reaction with ethanesulfonyl azide in the prese