54497-82-4Relevant articles and documents
Direct Decarboxylative Functionalization of Carboxylic Acids via O-H Hydrogen Atom Transfer
Na, Christina G.,Ravelli, Davide,Alexanian, Erik J.
supporting information, p. 44 - 49 (2020/01/22)
Decarboxylative functionalization via hydrogen atom transfer offers an attractive alternative to standard redox approaches to this important class of transformations. Herein, we report a direct decarboxylative functionalization of aliphatic carboxylic acids using N-xanthylamides. The unique reactivity of amidyl radicals in hydrogen atom transfer enables decarboxylative xanthylation under redox-neutral conditions. This platform provides expedient access to a range of derivatives through subsequent elaboration of the xanthate group.
An unusual route to deoxysugars by hydrogen atom transfer from cyclohexane. Possible manifestation of polar effects in a radical process
Quiclet-Sire, Béatrice,Zard, Samir Z.
, p. 9190 - 9191 (2007/10/03)
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