136408-30-5Relevant articles and documents
Pd-catalyzed asymmetric hydrogenation of C=C bond of α,β- unsaturated ketones
Wang, Duo-Sheng,Wang, Da-Wei,Zhou, Yong-Gui
, p. 947 - 950 (2011/06/17)
Homogenous palladium-catalyzed asymmetric hydrogenation of C=C double bond of ,-unsaturated ketones has been -developed by using palladium(II) trifluoroacetate/(S)-7,7-bis-[di(4-methoxyphenyl]phosphino)-1,1-spirobiindane complex [Pd(OCOCF3)2-(S)-An-SDP] as the catalyst under ambient hydrogen pressure and room temperature with up to 89% ee. Georg Thieme Verlag Stuttgart · New York.
Preparation and Reaction of Zinc and Copper Organometallics Bearing Acidic Hydrogens
Knoess, H. Peter,Furlong, Michael T.,Rozema, Michael J.,Knochel, Paul
, p. 5974 - 5978 (2007/10/02)
Organozinc and copper ragents bearing unprotected primary or secondary amines or amides or a terminal acetylenic proton were prepared and reacted with various electrophiles in good yields.