136408-30-5

Upstream product

• 122-57-6 1-Phenylbut-1-en-3-one 
• 931-50-0 cyclohexylmagnesium bromide 
• 87666-40-8 ethyl (2E)-3-cyclohexyl-3-phenyl prop-2-enoate 
• 712-50-5 Cyclohexyl phenyl ketone 
• 1193381-10-0 (E)-3-cyclohexyl-N-methoxy-N-methyl-3-phenylacrylamide 
• 626-62-0 Cyclohexyl iodide 
• 1896-62-4 (E)-benzalacetone 

Relevant academic research and scientific papers

Pd-catalyzed asymmetric hydrogenation of C=C bond of α,β- unsaturated ketones

Homogenous palladium-catalyzed asymmetric hydrogenation of C=C double bond of ,-unsaturated ketones has been -developed by using palladium(II) trifluoroacetate/(S)-7,7-bis-[di(4-methoxyphenyl]phosphino)-1,1-spirobiindane complex [Pd(OCOCF3)2-(S)-An-SDP] as the catalyst under ambient hydrogen pressure and room temperature with up to 89% ee. Georg Thieme Verlag Stuttgart · New York.

Conjugate Michael additions with mixed diorganozincs

Functionalised mixed alkyl(trimethylsilylmethyl)zinc reagents add efficiently to a wide variety of Michael acceptors in high yield and with exclusive 1,4-regioselectivity, without the need for transition metal catalysis. The trimethylsilylmethyl group behaves as a non-transferable group, and in no cases was transfer of this group observed.

Preparation and Reaction of Zinc and Copper Organometallics Bearing Acidic Hydrogens

Organozinc and copper ragents bearing unprotected primary or secondary amines or amides or a terminal acetylenic proton were prepared and reacted with various electrophiles in good yields.