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13642-97-2

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13642-97-2 Usage

Description

PENTAFLUOROPHENYL METHACRYLATE, also known as PFPMA, is a chemical compound that features a perfluorophenyl group and a methacrylate group. It is known for its unique properties, such as its reactivity in coupling reactions and its use in creating low refractive index polymers.

Uses

Used in Chemical Synthesis:
PENTAFLUOROPHENYL METHACRYLATE is used as an activated ester for coupling reactions, such as esterification and amidation. Its reactivity makes it a valuable component in the synthesis of various compounds and materials.
Used in Polymer Industry:
PENTAFLUOROPHENYL METHACRYLATE is used as a monomer for the production of low refractive index polymers, with a refractive index of approximately 1.40. These polymers have potential applications in the optical and electronics industries, where materials with specific refractive properties are required.

Check Digit Verification of cas no

The CAS Registry Mumber 13642-97-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,6,4 and 2 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 13642-97:
(7*1)+(6*3)+(5*6)+(4*4)+(3*2)+(2*9)+(1*7)=102
102 % 10 = 2
So 13642-97-2 is a valid CAS Registry Number.
InChI:InChI=1/C10H5F5O2/c1-3(2)10(16)17-9-7(14)5(12)4(11)6(13)8(9)15/h1H2,2H3

13642-97-2 Well-known Company Product Price

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  • Aldrich

  • (741108)  Pentafluorophenyl methacrylate  contains MEHQ as inhibitor, 95%

  • 13642-97-2

  • 741108-1G

  • 972.27CNY

  • Detail
  • Aldrich

  • (741108)  Pentafluorophenyl methacrylate  contains MEHQ as inhibitor, 95%

  • 13642-97-2

  • 741108-5G

  • 3,845.79CNY

  • Detail

13642-97-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (2,3,4,5,6-pentafluorophenyl) 2-methylprop-2-enoate

1.2 Other means of identification

Product number -
Other names Methacrylic acid,pentafluorophenyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13642-97-2 SDS

13642-97-2Related news

Optical and thermal properties of methyl methacrylate and PENTAFLUOROPHENYL METHACRYLATE (cas 13642-97-2) copolymer: Design of copolymers for low-loss optical fibers for gigabit in-home communications09/07/2019

As a novel base material for low-loss graded index plastic optical fibers (GI POFs) in gigabit home networks, a copolymer of methyl methacrylate (MMA) and pentafluorophenyl methacrylate (PFPMA) was prepared and its thermal and optical properties were investigated. When the PFPMA content in the m...detailed

13642-97-2Relevant articles and documents

Functional-Polymer Library through Post-Polymerization Modification of Copolymers Having Oleate and Pentafluorophenyl Pendants

Maiti, Binoy,Haldar, Ujjal,Rajasekhar, Tota,De, Priyadarsi

, p. 15156 - 15165 (2017)

Poly[2-(methacryloyloxy)ethyl oleate-co-pentafluorophenyl methacrylate] [P(MAEO-co-PFPMA)] random copolymers with oleate and pentafluorophenyl side-chain pendants were synthesized. These copolymers were utilized as dual-reactive polymeric scaffolds in a range of post-polymerization modification strategies involving thiol-ene and para-fluoro-thiol substitution, amidation, trans-esterification, and epoxidation followed by amidation. The 2-(methacryloyloxy)ethyl oleate (MAEO) functional handle in the copolymer is open to functionalization at its internal double bond through thermally initiated thiol-ene reaction, whereas the pentafluorophenyl moiety of the pentafluorophenyl methacrylate (PFPMA) unit undergoes para-fluoro-thiol substitution under basic conditions at room temperature. By means of these modification approaches, the P(MAEO-co-PFPMA) copolymer was orthogonally ligated with thiol compounds having, for example, alkyl, hydroxyl, and protected amine functional groups. Furthermore, different functional groups such as benzyl, allyl, methacrylate, pyrene, and water-soluble poly(ethylene glycol) were easily introduced into the side chain of the P(MAEO-co-PFPMA) copolymer by amidation, trans-esterification, and epoxidation followed by amidation. Functionalization of both the reactive pendants with the various organic substituents was confirmed by 1H and 19F NMR spectroscopy, gel permeation chromatography, and fluorescence spectroscopy.

FORCE-RESPONSIVE POLYMERSOMES AND NANOREACTORS; PROCESSES UTILIZING THE SAME

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Paragraph 0096, (2019/03/05)

The mechanically induced melting properties of DNA were employed to achieve force labile membranes is described. Nucleobase pairs were used as mechanophores. Adenine and thymine functionalized complementary amphiphilic block copolymers were self-assembled

Process for the preparation of halogenated (meth)acrylic esters and poly (meth) arcylates obtained with said (meth)acrylic esters

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, (2008/06/13)

The present invention is directed to a process for the preparation of (meth)acrylates of halogenated alcohols by direct esterification of said alcohols with (meth)acrylic acid (chloride) wherein at least 2,6-substituted pyridine derivative is used as a po

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