13642-97-2

Basic information

• Product Name: PENTAFLUOROPHENYL METHACRYLATE
• Synonyms: PENTAFLUOROPHENYL METHACRYLATE;Methacrylic acid 2,3,4,5,6-pentafluorophenyl ester;Pentafluorophenyl 2-methylprop-2-enoate;Methacrylic acid, pentafluorophenyl ester;Pentafluorophenyl Methacrylate (stabilized with MEHQ);Pentafluorophenyl methacrylate contains MEHQ as inhibitor, 95%;(2,3,4,5,6-pentafluorophenyl) 2-methylprop-2-enoate;Methacrylic acid pentafluorophenyl ester, 97%, stabilized with MEHQ
• CAS NO: 13642-97-2
• Molecular Formula: C₁₀H₅F₅O₂
• Molecular Weight: 252.14
• Product Categories: monomer
• Mol File: 13642-97-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 239.3°Cat760mmHg
• Flash Point: 77℃
• Appearance: /
• Density: 1.394 g/mL at 25 °C
• Vapor Pressure: 0.0404mmHg at 25°C
• Refractive Index: n20/D1.438
• Storage Temp.: Keep Cold
• CAS DataBase Reference: PENTAFLUOROPHENYL METHACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: PENTAFLUOROPHENYL METHACRYLATE(13642-97-2)
• EPA Substance Registry System: PENTAFLUOROPHENYL METHACRYLATE(13642-97-2)

Safety Data

• Hazard Codes: F,Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• RIDADR: NA 1993 / PGIII
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 13642-97-2(Hazardous Substances Data)

Usage

Description

PENTAFLUOROPHENYL METHACRYLATE, also known as PFPMA, is a chemical compound that features a perfluorophenyl group and a methacrylate group. It is known for its unique properties, such as its reactivity in coupling reactions and its use in creating low refractive index polymers.

Uses

Used in Chemical Synthesis:
PENTAFLUOROPHENYL METHACRYLATE is used as an activated ester for coupling reactions, such as esterification and amidation. Its reactivity makes it a valuable component in the synthesis of various compounds and materials.
Used in Polymer Industry:
PENTAFLUOROPHENYL METHACRYLATE is used as a monomer for the production of low refractive index polymers, with a refractive index of approximately 1.40. These polymers have potential applications in the optical and electronics industries, where materials with specific refractive properties are required.

InChI:InChI=1/C10H5F5O2/c1-3(2)10(16)17-9-7(14)5(12)4(11)6(13)8(9)15/h1H2,2H3

Upstream product

• 79-41-4 poly(methacrylic acid) 
• 771-61-9 2,3,4,5,6-pentafluorophenol 
• 920-46-7 Methacryloyl chloride 

Downstream Products

• 5438-81-3 3,3-dimethyl-1,4-diphenyl-azetidin-2-one 

Related news

Optical and thermal properties of methyl methacrylate and PENTAFLUOROPHENYL METHACRYLATE (cas 13642-97-2) copolymer: Design of copolymers for low-loss optical fibers for gigabit in-home communications09/07/2019

As a novel base material for low-loss graded index plastic optical fibers (GI POFs) in gigabit home networks, a copolymer of methyl methacrylate (MMA) and pentafluorophenyl methacrylate (PFPMA) was prepared and its thermal and optical properties were investigated. When the PFPMA content in the m...detailed

Relevant articles and documents

Functional-Polymer Library through Post-Polymerization Modification of Copolymers Having Oleate and Pentafluorophenyl Pendants

Poly[2-(methacryloyloxy)ethyl oleate-co-pentafluorophenyl methacrylate] [P(MAEO-co-PFPMA)] random copolymers with oleate and pentafluorophenyl side-chain pendants were synthesized. These copolymers were utilized as dual-reactive polymeric scaffolds in a range of post-polymerization modification strategies involving thiol-ene and para-fluoro-thiol substitution, amidation, trans-esterification, and epoxidation followed by amidation. The 2-(methacryloyloxy)ethyl oleate (MAEO) functional handle in the copolymer is open to functionalization at its internal double bond through thermally initiated thiol-ene reaction, whereas the pentafluorophenyl moiety of the pentafluorophenyl methacrylate (PFPMA) unit undergoes para-fluoro-thiol substitution under basic conditions at room temperature. By means of these modification approaches, the P(MAEO-co-PFPMA) copolymer was orthogonally ligated with thiol compounds having, for example, alkyl, hydroxyl, and protected amine functional groups. Furthermore, different functional groups such as benzyl, allyl, methacrylate, pyrene, and water-soluble poly(ethylene glycol) were easily introduced into the side chain of the P(MAEO-co-PFPMA) copolymer by amidation, trans-esterification, and epoxidation followed by amidation. Functionalization of both the reactive pendants with the various organic substituents was confirmed by 1H and 19F NMR spectroscopy, gel permeation chromatography, and fluorescence spectroscopy.

FORCE-RESPONSIVE POLYMERSOMES AND NANOREACTORS; PROCESSES UTILIZING THE SAME

The mechanically induced melting properties of DNA were employed to achieve force labile membranes is described. Nucleobase pairs were used as mechanophores. Adenine and thymine functionalized complementary amphiphilic block copolymers were self-assembled

Process for the preparation of halogenated (meth)acrylic esters and poly (meth) arcylates obtained with said (meth)acrylic esters

The present invention is directed to a process for the preparation of (meth)acrylates of halogenated alcohols by direct esterification of said alcohols with (meth)acrylic acid (chloride) wherein at least 2,6-substituted pyridine derivative is used as a po