136457-46-0Relevant academic research and scientific papers
AMINOSULFENYLATION OF OLEFINS BY N,N'-THIO- AND N,N'-DITHIOBIS(DIALKYLAMINES)
Petrov, K. A.,Rudnev, G. V.,Sorokin, V. D.
, p. 1791 - 1794 (2007/10/02)
The reaction of N,N'-thio- and N,N'-dithiobis(dialkylamines) with olefins (ethylene, cyclohexene, styrene) in the presence of Lewis acids leads to the products from 1,2-addition at the double bond of the olefin.In the presence of boron trifluoride etherate bis(2-dialkylaminoalkyl) disulfides and sulfides are formed.The use of zinc chloride leads to N-(2-dialkylaminoalkylthio)- and N-(2-dialkylaminoalkyldithio)dialkylamines.
