1365543-21-0

Basic information

• Product Name: C₁₅H₂₇B₃O₃
• CAS NO: 1365543-21-0
• Molecular Weight: 287.811
• Mol File: 1365543-21-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₅H₂₇B₃O₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₂₇B₃O₃(1365543-21-0)
• EPA Substance Registry System: C₁₅H₂₇B₃O₃(1365543-21-0)

Safety Data

• Hazardous Substances Data: 1365543-21-0(Hazardous Substances Data)

Upstream product

• 52340-78-0 (R,R)-hydroxybenzoin 
• 63076-51-7 cyclopentane boronic acid 
• 120-80-9 benzene-1,2-diol 

Relevant articles and documents

Mechanism and optimisation of the homoboroproline bifunctional catalytic asymmetric aldol reaction: Lewis acid tuning through in situ esterification

The use of homoboroproline as a bifunctional catalyst in the asymmetric aldol reaction has been investigated mechanistically, particularly with respect to tuning the Lewis acidity of boron by in situ esterification with mildly sigma-electron withdrawing diols such as hydrobenzoin and tartrate esters. The stability of simple cyclohexyl and cyclopentyl boronate diol esters shows that the 5-ring boronate esters are more stable, which sheds light on the mode of action of esterified homoboroproline catalyst in the enamine-mediated aldol reaction, which is also studied by NMR. The result is reaction optimisation to provide an efficient aldol reaction and a proposed mechanistic proposal. The Royal Society of Chemistry 2012.