1365565-21-4Relevant academic research and scientific papers
Competitive [2,3]-and [1,2]-oxonium ylide rearrangements. Concerted or stepwise?
Jaber, Deana M.,Burgin, Ryan N.,Helper, Matthew,Zavalij, Peter Y.,Doyle, Michael P.
, p. 1676 - 1679 (2012)
The axial-equatorial conformational isomer distribution of the reactant diazoacetoacetate or its metal carbene intermediate is reflected in Rh(II) catalyzed oxonium ylide forming reactions of 3-(trans-2-arylvinyl) tetrahydropyranone-5-diazoacetoacetates that afford diastereoisomeric products for both the symmetry-allowed [2,3]-and the formally symmetry-forbidden [1,2]-oxonium ylide rearrangements.
