1365566-08-0Relevant articles and documents
Carbocyclization cascades of allyl ketenimines via aza-Claisen rearrangements of N-phosphoryl-N-allyl-ynamides
Dekorver, Kyle A.,Wang, Xiao-Na,Walton, Mary C.,Hsung, Richard P.
, p. 1768 - 1771 (2012)
A series of carbocyclization cascades of allyl ketenimines initiated through a thermal aza-Claisen rearrangement of N-phosphoryl-N-allyl ynamides is described. Interceptions of the cationic intermediate via Meerwein-Wagner rearrangements and polyene-type cyclizations en route to fused bi-and tricyclic frameworks are featured.