136579-79-8Relevant academic research and scientific papers
Intermodular Mn(OAc)3-mediated oxidative free-radical reaction of dimethyl malonate or ethyl cyanoacetate with allenes: An efficient synthesis of furan-2(5H)-ones or dimethyl 2-(2-oxoethylidene)malonates
Wu, Zhimeng,Huang, Xian
, p. 45 - 50 (2007)
Manganese(III)-mediated free-radical reaction of allenes with dimethyl malonate or ethyl cyanoacetate in acetic acid produces furan-2-(5H)-one derivatives (but-2-en-4-olides) or dimethyl 2-(2-oxoethylidene)malonates in moderate yields. The possible reacti
Photosensitized oxidation of furans; Part 18: A simple method for a one-pot synthesis of functionalized methyl cis-4-oxoalk-2-enoates
Iesce,Cermola,Piazza,Scarpati,Graziano
, p. 439 - 443 (2007/10/02)
Functionalized methyl cis-4-oxoalk-2-enoates 2 are synthesized in a one-pot procedure by singlet oxygen oxygenation of the corresponding 2-methoxyfurans 1 in methanol and reduction of the resulting hydroperoxides 4 and 5 by the sulfides 6 which are selectively oxidized into the sulfoxides 7. The synthetic method has a wide range of applicability and affords compounds 2 stereoselectively and in good yields; concomitantly the sulfoxides 7 are obtained in excellent yields.
A Further Selective Pathway in Thermal Conversion of 2,5-Epidioxy-2-alkoxy-2,5-dihydrofurans (2-Alkoxyfuran endo-Peroxides). Synthesis of the First 5-Hydroperoxyfuran-2(5H)-ones
Iesce, M. Rosaria,Graziano, M. Liliana,Cermola, Flavio,Scarpati, Rachele
, p. 1061 - 1062 (2007/10/02)
Thermal conversion of the epidioxydihydrofurans 1 leads, via dioxyetanes 3, to the stereoisomeric dimers 4 which have a structural relationship with antitumor cyclic peroxides and represent convenient starting materials for several multifunctional compoun
