136579-82-3

Basic information

• Product Name: 5-Hydroperoxy-4-methyl-2-oxo-5-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester
• CAS NO: 136579-82-3
• Molecular Weight: 264.235
• Mol File: 136579-82-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-Hydroperoxy-4-methyl-2-oxo-5-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hydroperoxy-4-methyl-2-oxo-5-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester(136579-82-3)
• EPA Substance Registry System: 5-Hydroperoxy-4-methyl-2-oxo-5-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester(136579-82-3)

Safety Data

• Hazardous Substances Data: 136579-82-3(Hazardous Substances Data)

Upstream product

• 135462-54-3 methyl 5-hydroperoxy-2,2-dimethoxy-4-methyl-5-phenyl-2,5-dihydrofuran-3-carboxylate 
• 135462-61-2 methyl 2-methoxy-4-methyl-5-phenyl-furan-3-carboxylate 
• 673-32-5 1-Phenylprop-1-yne 

Downstream Products

• 136579-84-5 5-Hydroxy-4-methyl-2-oxo-5-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester 

Relevant articles and documents

Photosensitized oxidation of furans; part 17: A simple method for the synthesis of 5-hydroperoxyfuran-2(5H)-ones

The 5-hydroperoxyfuran-2(5H)-ones 3 are synthesized by acid hydrolysis of the dihydrofurans 1 which are prepared in one-pot procedure by reaction of the corresponding furans 4 with singlet oxygen and methanol. The synthetic method has a wide range of applicability; however, compounds 3 unsubstituted at C-4 cannot be prepared since the corresponding dihydrofurans 1 are not formed.