135462-54-3Relevant academic research and scientific papers
Photosensitized oxidation of furans; part 17: A simple method for the synthesis of 5-hydroperoxyfuran-2(5H)-ones
Iesce,Cermola,Graziano,Scarpati
, p. 944 - 948 (2007/10/02)
The 5-hydroperoxyfuran-2(5H)-ones 3 are synthesized by acid hydrolysis of the dihydrofurans 1 which are prepared in one-pot procedure by reaction of the corresponding furans 4 with singlet oxygen and methanol. The synthetic method has a wide range of applicability; however, compounds 3 unsubstituted at C-4 cannot be prepared since the corresponding dihydrofurans 1 are not formed.
Photosensitized Oxidation of Furans. Part 15. Limitations to the Formation of Carbonyl Oxides from 2-Alkoxyfurans, and Direct Evidence for the First 3H-1,2-Dioxole
Graziano, M. Liliana,Iesce, M. Rosaria,Cermola, Flavio,Cimminiello, Guido,Scarpati, Rachele
, p. 1479 - 1484 (2007/10/02)
Formation of the carbonyl oxides 3, via the furan endo-peroxides 1, can be accomplished only by dye-sensitized photo-oxygenation of 2-alkoxyfurans 2 unsubstituted at C-4, electron-withdrawing substituents at C-3 making the formation selective.Hydrogen or
A Further Selective Pathway in Thermal Conversion of 2,5-Epidioxy-2-alkoxy-2,5-dihydrofurans (2-Alkoxyfuran endo-Peroxides). Synthesis of the First 5-Hydroperoxyfuran-2(5H)-ones
Iesce, M. Rosaria,Graziano, M. Liliana,Cermola, Flavio,Scarpati, Rachele
, p. 1061 - 1062 (2007/10/02)
Thermal conversion of the epidioxydihydrofurans 1 leads, via dioxyetanes 3, to the stereoisomeric dimers 4 which have a structural relationship with antitumor cyclic peroxides and represent convenient starting materials for several multifunctional compoun
