1366246-40-3

Upstream product

• 1385018-40-5 (R,Z)-6-((4-methoxybenzyl)oxy)-2-methylhex-4-enal 
• 1366246-39-0 C₁₅H₂₀O₃ 
• 1366246-17-4 (4S)-4-benzyl-3-[(2S,3R,4R,6Z)-3-hydroxy-8-[(4-methoxyphenyl)methoxy]-2,4-dimethyloct-6-enoyl]-1,3-oxazolidin-2-one 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 1366246-14-1 (2R,4Z)-6-[(4-methoxyphenyl)methoxy]-2-methylhex-4-en-1-ol 
• 1366246-12-9 1-methoxy-4-({[(5R)-5-methyl-6-(triphenylmethoxy)hexyl]oxy}methyl)benzene 

Downstream Products

• 1366246-50-5 C₅₄H₈₆O₈Si₂ 
• 1366246-19-6 (2R,3R,4R,6Z)-3-[(tert-butyldimethylsilyl)oxy]-8-[(4-methoxyphenyl)methoxy]-2,4-dimethyloct-6-en-1-ol 
• 1366246-21-0 (4S,5R,6R,7R,9Z)-6-[(tert-butyldimethylsilyl)oxy]-11-[(4-methoxyphenyl)methoxy]-5,7-dimethylundec-9-en-1-yn-4-ol 
• 1366246-76-5 (5S,6R,7R,8R,10Z)-7-[(tert-butyldimethylsilyl)oxy]-12-[(4-methoxyphenyl)methoxy]-6,8-dimethyldodec-10-en-2-yn-5-ol 
• 1366246-52-7 (5S,6R,7R,8R,10Z)-7-[(tert-butyldimethylsilyl)oxy]-12-[(4-methoxyphenyl)methoxy]-6,8-dimethyldodec-10-en-2-yn-5-yl 2-hydroxy-4-methoxy-6-[(2R,3S)-3-methyl-2-{[tris(propan-2-yl)silyl]oxy}hept-5-yn-1-yl]benzoate 
• 1366246-24-3 (5S,6R,7R,8R,10Z)-7-[(tert-butyldimethylsilyl)oxy]-12-[(4-methoxyphenyl)methoxy]-6,8-dimethyldodec-10-en-2-yn-5-yl 2,4-dihydroxy-6-[(2R,3S)-3-methyl-2-{[tris(propan-2-yl)silyl]oxy}hept-5-yn-1-yl]benzoate 
• 1366246-26-5 C₅₀H₈₀O₈Si₂ 

Relevant academic research and scientific papers

Biomimetic total synthesis of cruentaren A via aromatization of diketodioxinones

The total synthesis of cruentaren A, a biologically active resorcylate natural product, is reported. The aromatic unit was constructed via late-stage cyclization and aromatization from a diketodioxinone intermediate and macrocyclization using Fuerstner ring-closing alkyne metathesis.