1366246-12-9Relevant articles and documents
Biomimetic total synthesis of cruentaren A via aromatization of diketodioxinones
Fouche, Marianne,Rooney, Lisa,Barrett, Anthony G. M.
, p. 3060 - 3070 (2012/05/20)
The total synthesis of cruentaren A, a biologically active resorcylate natural product, is reported. The aromatic unit was constructed via late-stage cyclization and aromatization from a diketodioxinone intermediate and macrocyclization using Fuerstner ring-closing alkyne metathesis.