13672-84-9Relevant academic research and scientific papers
Hypervalent iodine-catalyzed oxylactonization of ketocarboxylic acids to ketolactones
Uyanik, Muhammet,Yasui, Takeshi,Ishihara, Kazuaki
supporting information; experimental part, p. 3848 - 3851 (2010/03/03)
The hypervalent iodine-catalyzed oxylactonization of ketocarboxylic acids to ketolactones was achieved in the presence of iodobenzene (10 mol %), p-toluenesulfonic acid monohydrate (20 mol %) and meta-chloroperbenzoic acid as a stoichiometric co-oxidant.
Preparation and Thermolysis of cis- and trans-1-Hydroxy-2-(2-pyridyl)cyclopentanes and cis- and trans-1-Hydroxy-2-(2-pyrazyl)cyclopentanes
Houminer, Yoram
, p. 786 - 789 (2007/10/02)
The syntheses of cis- and trans-1-hydroxy-2-(2-pyridyl)cyclopentanes as well as cis- and trans-1-hydroxy-2-(2-pyrazyl)cyclopentanes have been carried out, and their stereochemical assignments were done by using IR and NMR data.The thermolyses of these pyrazylethanols and pyridylethanols have been studied in diglyme solutions at 170 deg C.While the pyrazylethanols mainly undergo dehydration, the pyridylethanols thermolyze via a much more complex reaction process.
