136786-36-2

Upstream product

• 136262-55-0 (2E,5S)-6-(tert-butyldiphenylsilyloxy)-5-methylhex-2-en-1-ol 
• 910043-29-7 (2S,4E)-6-[(4-methoxyphenyl)methoxy]-2-methylhex-4-en-1-ol 
• 910043-07-1 (2R,3R,5S)-1-(benzyloxy)-6-(tert-butyldiphenylsilyloxy)-2,3-epoxy-5-methylhexane 
• 75-24-1 trimethylaluminum 

Downstream Products

• 136786-39-5 benzyl [6-(tert-butyldiphenylsilyloxy)-3(S),5(S)-dimethyl-2(S)-(methoxymethoxy)hex-1-yl] ether 
• 136786-41-9 tert-Butyl-[(6E,8E,10E)-(2S,4S,5S)-12-(4-methoxy-benzyloxy)-5-methoxymethoxy-2,4,10-trimethyl-dodeca-6,8,10-trienyloxy]-diphenyl-silane 
• 910042-96-5 6-{(1E,3S,5S,6S,7E,9E,11E)-[13-(4-methoxybenzyloxy)-6-(methoxymethoxy)-1,3,5,11-tetramethyltrideca-1,7,9,11-tetraen-1-yl]}-2,2-dimethyl-4H-1,3-dioxen-4-one 
• 136786-40-8 (2S,3S,5S)-6-(tert-butyldiphenylsilyloxy)-3,5-dimethyl-2-(methoxymethoxy)hexanal 
• 910043-30-0 (2S,4S,5S,6E,8E,10E)-12-(4-methoxybenzyloxy)-5-(methoxymethoxy)-2,4,10-trimethyldodeca-6,8,10-trienal 
• 910043-13-9 (2S,4S,5S,6E,8E,10E)-12-(4-methoxybenzyloxy)-5-(methoxymethoxy)-2,4,10-trimethyldodeca-6,8,10-trien-1-ol 
• 910043-08-2 6-(tert-butyldiphenylsilyloxy)-3(S),5(S)-dimethyl-2(S)-(methoxymethoxy)hexan-1-ol 

Relevant academic research and scientific papers

Toward the development of a general chiral auxiliary. A total synthesis of (+)-tetronolide via a tandem ketene-trapping [4 + 2] cycloaddition strategy

A highly convergent, enantioselective total synthesis of the aglycone of the tetrocarcins, (+)-tetronolide, is described. The synthesis highlights the use of several new methods, including camphor auxiliary-directed asymmetric alkylation and the enantiose