136808-92-9Relevant academic research and scientific papers
Stereoselective synthesis of substituted tetrahydrofurans - Identification and analysis by proton NMR and MNDO, MM2 calculations
Tarakeshwar,Iqbal, Javed,Manogaran
, p. 297 - 304 (1991)
Methyl acetoacetate and terminal olefins react in the presence of cobalt(II) acetate and oxygen to give 5-alkyl-2-hydroxy-2-methyl-3-methoxycarbonyl tetrahydrofurans in a highly stereoselective manner. Proton NMR, semiempirical MNDO and empirical MM2 methods are used to identify the particular diastereomer and the energetics of the different isomers are discussed.
Cobalt(II)acetate promoted oxidative addition of 1,3-dicarbonyl compounds to alkenes under aerobic conditions
Iqbal,Bhatia,Nayyar
, p. 6457 - 6468 (2007/10/02)
The reaction of 1,3-dicarbonyl compounds with various alkenes in presence of Co(OAC)2. XH2O under aerobic conditions gives dihydrofurans in moderate to good yields. The role of dioxygen is discussed by comparing these reactions under
COBALT(II) ACETATE PROMOTED ADDITION OF ACETOACETATE TO TERMINAL OLEFINS: A HIGHLY STEREOSELECTIVE SYNTHESIS OF 5-ALKYL-2-HYDROXY-2-METHYL-3-METHOXYCARBONYL TETRAHYDROFURANS
Iqbal, Javed,Kumar, T. K. Praveen,Manogaran, S.
, p. 4701 - 4702 (2007/10/02)
Methylacetoacetate and terminal olefins react in presence of Cobalt(II) acetate and Oxygen to give the title compound(2) in a highly stereoselective manner and the structure of this compound is elucidated by 1H NMR simulation studies.
