136835-32-0Relevant academic research and scientific papers
A useful synthesis of (R,R)-1,2-ethanediylbis[(o-methoxyphenyl)phenylphosphine] the ligand of the enantioselective catalyst [Rh(COD) (DIPAMP)]+ BF4-
Schmidt,Riedl,Griesser,Fitz
, p. 655 - 657 (1991)
1,2-Ethanediylbis[(o-methoxyphenyl)phenylphosphine] the ligand of the enantioselective catalyst [Rh(1,5-COD)(DIPAMP)]+ BF4- is prepared from (1S)-bornyl (R)p-methyl(phenyl)phosphinate, which is diastereoselectively formed.
Dynamic Kinetic Resolution of Phosphinic Acid Derivatives via Nucleophilic Substitution at Phosphorus Center
Strzelecka, Dorota,Baok, Olga,Borowski, Piotr,Stankevi?, Marek
supporting information, p. 4922 - 4932 (2018/12/14)
Reaction of racemic phosphinic acid derivatives with chiral alcohols proceeds with predominant formation of one diastereomer. The highest level of enrichment has been obtained for transesterfication of racemic methyl benzylphenylphosphinate (64% de). The
A generalization of the base effect on the diastereoselective synthesis of sulfinic and phosphinic esters
Fernandez, Inmaculada,Khiar, Noureddine,Roca, Aranzazu,Benabra, Abdelhak,Alcudia, Ana,Espartero, Jose L.,Alcudia, Felipe
, p. 2029 - 2032 (2007/10/03)
Various chiral secondary alcohols have been used to study the dependence of the stereochemical outcome of sulfinate and phosphinate ester synthesis on the nature of the base used to catalyse the reaction. From this study it has been shown that the achiral
