136847-29-5Relevant academic research and scientific papers
Sorption properties toward environmentally important VOCs of half-sandwich Ru(II) complexes containing perylene bisimide ligands
Pagano, Paolo,Pelagatti, Paolo,Bacchi, Alessia,Chierotti, Michele R.,Bourne, Susan A.,Mehlana, Gift
, p. 427 - 432 (2017)
Two py-functionalized perylene bisimide ligands were synthesized and used to make bimetallic halfsandwich Ru(II) complexes. These were characterized by IR, 1H NMR, 13C CPMAS SSNMR spectroscopy, and elemental analysis. The complexes are wheel-and-axle (waa) compounds, where the axle is the divergent ligand and the wheels are the [(p-cymene)RuCl2] units. The complexes, but not the free ligands, showed absorption of volatile organic compounds such as toluene and xylenes through heterogeneous solid/gas uptakes. The reactivity is ascribable to the waa geometry, likely by an upset of the high stacking characterizing the crystalline frameworks of the free ligands. The kinetic profiles of the uptake reactions were determined
Fast and Efficient Microwave-Assisted Synthesis of Perylenebisimides
Rigodanza, Francesco,Tenori, Eleonora,Bonasera, Aurelio,Syrgiannis, Zois,Prato, Maurizio
, p. 5060 - 5063 (2015)
Perylene-3,4,9,10-tetracarboxylic acid bisimides have been widely studied as industrial pigments. Lately, these dyes have drawn considerable attention because of applications as photocatalysts and organic semi-conductors. Here, we report a novel method fo
