136912-02-2

Basic information

• Product Name: Toluene-4-thiosulfonic acid S-[(3S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester
• CAS NO: 136912-02-2
• Molecular Weight: 556.918
• Mol File: 136912-02-2.mol

Chemical Properties

• CAS DataBase Reference: Toluene-4-thiosulfonic acid S-[(3S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester(CAS DataBase Reference)
• NIST Chemistry Reference: Toluene-4-thiosulfonic acid S-[(3S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester(136912-02-2)
• EPA Substance Registry System: Toluene-4-thiosulfonic acid S-[(3S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl] ester(136912-02-2)

Safety Data

• Hazardous Substances Data: 136912-02-2(Hazardous Substances Data)

Upstream product

• 136911-96-1 Trifluoro-methanesulfonate2-[(3S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yldisulfanyl]-1-methyl-pyridinium; 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 1249-81-6 thiocholesterol 
• 136911-91-6 cholest-5-en-3-β-yl 2-pyridyl disulfide 

Relevant articles and documents

A New Procedure for the Conversion of Thiols into Reactive Sulfenylating Agents

Thiols may be converted in high yield into unsymmetrical 2-pyridyl disulfides 3.Treatment of these with alkylating agents (e.g., alkyl fluorosulfonates or oxonium salts) affords the corresponding N-alkylpyridyl disulfides 4, which are potent sulfenylating agents (Scheme II) and react smoothly with a variety of sulfur nucleophiles (e.g., thiols, thiones, thioamides, dithiocarbamates, thiocyanate, etc.) to afford disulfides, with amines to afford sulfenamides, and with β-diketones to afford sulfides.This new method is particularly well-suited to the preparation of unsymmetrical disulfides and sulfenamides from complex and otherwise r eactive thiols.