136914-80-2Relevant articles and documents
1,2-Stereoinduction in Radicals and Anions: A Comparison between Hydrogen Abstraction and Protonation
Erdmann, Peter,Schaefer, Joerg,Springer, Ronald,Zeitz, Heinz-Georg,Giese, Bernd
, p. 638 - 644 (1992)
Chiral enolates 5 and 10, generated by radical addition and subsequent reduction, show diastereofacial selectivity during protonation.In the presence of substituted amines, diastereoselectivity is enhanced and becomes comparable to radical stereoselection