1,2-Stereoinduction in Radicals and Anions: A Comparison between Hydrogen Abstraction and Protonation

DOI: 10.1002/hlca.19920750219

Source and publish data:

Helvetica Chimica Acta p. 638 - 644 (1992)

Update date:2022-08-05

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Authors:

Erdmann, Peter

Schaefer, Joerg

Springer, Ronald

Zeitz, Heinz-Georg

Giese, Bernd

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Article abstract of DOI:10.1002/hlca.19920750219

Chiral enolates 5 and 10, generated by radical addition and subsequent reduction, show diastereofacial selectivity during protonation.In the presence of substituted amines, diastereoselectivity is enhanced and becomes comparable to radical stereoselection

Full text of DOI:10.1002/hlca.19920750219

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